| Title | 4-tert-Butyl-2-[2-(1,3,3-trimethylindolin-2-ylidene)ethylidene] cyclohexanone |
| Publication Type | Journal Article |
| Year of Publication | 2011 |
| Authors | Gainsford, G. J., Ashraf M., and Kay A. J. |
| IRL Team | Carbohydrate Chemistry |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 67 |
| Pagination | o1210 |
| Abstract | The title molecule, C23H31NO, has two alternative cyclohexanone configurations at the 4-position in a ratio of 0.663 (3):0.337 (3). The plane of the five-membered planar ring in the indolin-2-ylidene subtends an angle of 2.19 (7)° with its fused aromatic ring, an angle of 16.24 (8)° with the plane of the major cyclohexanone configuration and an angle of 8.54 (15)° with the bridging planar ethylidene C atoms. These last atoms subtend an angle of 8.37 (16)° with the mean plane through the major cyclohexanone configuration. The molecules pack approximately parallel to the (101) plane via C-H⋯π and C-H⋯O interactions. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-79955600314&partnerID=40&md5=2015fd81330591a06bc6ef24857867b3 |
| DOI | 10.1107/S1600536811014590 |
