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Low frequency Raman modes of Bi2-xPbxSr 1:6Ln0:4CuO6-δ

TitleLow frequency Raman modes of Bi2-xPbxSr 1:6Ln0:4CuO6-δ
Publication TypeJournal Article
Year of Publication2012
AuthorsMallett, B. P. P., Schnyder T., Williams G. V. M., and Tallon J. L.
JournalMaterials Science Forum
Volume700
Pagination11-14
ISSN02555476
ISBN Number9783037852637
KeywordsApical oxygen, Bi-2201, Bi-based, Doping state, Experimental errors, Lead, Low-frequency Raman, Lower frequencies, Nanotechnology, Polycrystalline, Polycrystalline materials, Raman measurements, Raman modes, Unit cells
Abstract Raman measurements were made on polycrystalline Bi2-xPb xSr1:6Ln0:4CuO6-δ for Ln=fLa, Nd, Sm, Eug with various x and doping states. Our measurements suggest a significant Bi contribution to the 118cm-1 mode but not to the 70cm-1 mode which instead shifts to lower frequencies with increasing number of CuO2 layers in the Bi-based family. Shifts in the O(2)Sr apical oxygen mode can be attributed to unit cell contraction within experimental error. © (2012) Trans Tech Publications, Switzerland.
URLhttp://www.scopus.com/inward/record.url?eid=2-s2.0-80053934755&partnerID=40&md5=3dd630f6b89e10d4f1fac2d02f8d1fe6
DOI10.4028/www.scientific.net/MSF.700.11